The step-wise assembly of an undecanuclear heterotrimetallic cyanide cluster.

نویسندگان

  • Curtis P Berlinguette
  • Kim R Dunbar
چکیده

The step-wise assembly of the high nuclearity cluster, {[Ni(II)(H2O)5]6[Co(III)(tmphen)2]3[Fe(II)(CN)6]2}13+, is achieved by treating {[Co(tmphen)2]3[Fe(CN)6]2} with six equivalents of Ni(ClO4)2 in aqueous MeOH.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A star-shaped ruthenium complex with five ferrocenyl-terminated arms bridged by trans-platinum fragments.

We present the synthesis of the new heteropolytopic penta(4-ethynylphenyl)cyclopentadiene ligand, its complexation through the Cp ring to ruthenium tris(indazolyl)borate and through the terminal alkyne groups to five ferrocenyl ethynyl platinum units, yielding an undecanuclear heterotrimetallic complex.

متن کامل

An unprecedented heterotrimetallic Fe/Cu/Co core for mild and highly efficient catalytic oxidation of cycloalkanes by hydrogen peroxide.

An unprecedented hexanuclear heterotrimetallic Fe/Cu/Co complex bearing two Cu(mu-O)2Co(mu-O)2Fe cores is easily prepared by self-assembly and acts as a remarkable catalyst for the peroxidative oxidation of cycloalkanes under mild conditions.

متن کامل

Self-assembly of the unique heterotrimetallic Cu/Co/M complexes possessing triangular antiferromagnetic {Cu2CoPb}2 and linear ferromagnetic {Cu2CoCd2} cores.

Two novel heterotrimetallic octa-[Cu2CoPbCl4(L)4]2 (1) and pentanuclear [Cu2CoCd2Cl6(L)4(HOMe)2] (2) complexes have been prepared in one-pot reactions of zerovalent copper with metal chlorides in a methanol (for 1) or acetonitrile (for 2) solution of 2-(dimethylamino)ethanol (HL) in open air. The crystal structures of both compounds consist of discrete centrosymmetric heterotrimetallic molecule...

متن کامل

Fuzzy multi-objective assembly line balancing problem: Fuzzy mathematical programming approach

Design of assembly line is done in order to more coordinate a collection of some consecutive work stations for the aim of obtaining more productivity from the work stations and workers. The stations are arranged in a way to have a continuous and constant material flow. In this paper a multi-objective formulation for assembly line balancing is introduced. As a solution approach a two-step approa...

متن کامل

Enhanced aldolase activity and glycolysis as short term effects of hydrogen cyanide for the release of dormancy in walnut kernels

Seed dormancy removal by cold stratification is accompanied by the development of gluconeogenic competence. Although hydrogen cyanide can stimulate the germination of many herbaceous dormant seeds and increase gluconeogenesis in long term, its short-term effects on sugar metabolism require further investigation. Accordingly, an experiment in the form of complete randomized design was carried ou...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 19  شماره 

صفحات  -

تاریخ انتشار 2005